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71.
72.
《Ceramics International》2022,48(17):24888-24897
In the furnace cycle test, the growth of oxide film leads to the propagation and coalescence of multiple cracks near the interface, which should be responsible for the spallation of thermal barrier coatings (TBCs). A TBC model with real interface morphology is created, and the near-interface large pore is retained. The purpose of this work is to clarify the mechanism of TBC spallation caused by successive initiation, propagation, and linkage of cracks near the interface during thermal cycle. The dynamic growth of thermally grown oxide (TGO) is carried out by applying a stress-free strain. The crack nucleation and arbitrary path propagation in YSZ and TGO are simulated by the extended finite element method (XFEM). The debonding along the YSZ/TGO/BC interface is evaluated using a surface-based cohesive behavior. The large-scale pore in YSZ near the interface can initiate a new crack. The ceramic crack can propagate to the YSZ/TGO interface, which will accelerate the interfacial damage and debonding. For the TGO/BC interface, the normal compressive stress and small shear stress at the valley hinder the further crack propagation. The growth of YSZ crack and the formation of through-TGO crack are the main causes of TBC delamination. The accelerated BC oxidation increases the lateral growth strain of TGO, which will promote crack propagation and coalescence. The optimization design proposed in this work can provide another option for developing TBC with high durability. 相似文献
73.
《Journal of the European Ceramic Society》2022,42(8):3559-3569
To explore the mechanism of phase transformation, YTa3O9 was prepared by an integrated one-step synthesis and sintering method at 1500 °C using Y2O3 and Ta2O5 powders as starting materials. High-temperature XRD patterns and Raman spectra showed that a phase transformation from orthorhombic to tetragonal took place in YTa3O9 through the bond length and angle changes at 300–400 °C, which caused a thermal conductivity rise. To inhibit the phase transformation, a high-entropy (Y0.2La0.2Ce0.2Nd0.2Gd0.2)Ta3O9 (HE RETa3O9) was designed and synthesized at 1550 °C using the integrated solid-state synthesis and sintering method. In tetragonal structured HE RETa3O9, phase transformation was inhibited by the high-entropy effect. Furthermore, HE RETa3O9 exhibited low thermal conductivity, and its tendency to increase with temperature was alleviated (1.69 W/m·K, 1073 K). Good phase stability, low thermal conductivity and comparable fracture toughness to YSZ make HE RETa3O9 promising as a new thermal barrier coating material. 相似文献
74.
以某大型钢结构制造企业为例,通过对产量分布、质量控制、劳动效率等基本数据的分析,研判外协生产管理体系方面存在的问题,从组织形态、管理模式、职能管理等多个维度提出了可行性建议,可为同类型钢结构制造企业提供经验借鉴。 相似文献
75.
Valentina Tedeschi Giorgia Paldino Fabiana Paladini Benedetta Mattorre Loretta Tuosto Rosa Sorrentino Maria Teresa Fiorillo 《International journal of molecular sciences》2020,21(24)
The strong association with the Major Histocompatibility Complex (MHC) class I genes represents a shared trait for a group of autoimmune/autoinflammatory disorders having in common immunopathogenetic basis as well as clinical features. Accordingly, the main risk factors for Ankylosing Spondylitis (AS), prototype of the Spondyloarthropathies (SpA), the Behçet’s disease (BD), the Psoriasis (Ps) and the Birdshot Chorioretinopathy (BSCR) are HLA-B*27, HLA-B*51, HLA-C*06:02 and HLA-A*29:02, respectively. Despite the strength of the association, the HLA pathogenetic role in these diseases is far from being thoroughly understood. Furthermore, Genome-Wide Association Studies (GWAS) have highlighted other important susceptibility factors such as Endoplasmic Reticulum Aminopeptidase (ERAP) 1 and, less frequently, ERAP2 that refine the peptidome presented by HLA class I molecules to CD8+ T cells. Mass spectrometry analysis provided considerable knowledge of HLA-B*27, HLA-B*51, HLA-C*06:02 and HLA-A*29:02 immunopeptidome. However, the combined effect of several ERAP1 and ERAP2 allelic variants could generate an altered pool of peptides accounting for the “mis-immunopeptidome” that ranges from suboptimal to pathogenetic/harmful peptides able to induce non-canonical or autoreactive CD8+ T responses, activation of NK cells and/or garbling the classical functions of the HLA class I molecules. This review will focus on this class of epitopes as possible elicitors of atypical/harmful immune responses which can contribute to the pathogenesis of chronic inflammatory diseases. 相似文献
76.
化学强化是一种玻璃机械强度增强方法,适用于异型、超薄、高碱、高膨胀玻璃增强,因新型超薄显示产品的屏幕保护玻璃发展需要,化学强化技术重新在碱铝硅酸盐玻璃品种掀起研究热潮。本文对化学强化本质及铝硅酸盐玻璃在屏幕保护玻璃应用进行了回顾,基于玻璃化学强化的高CS、DOL和低CT诉求,归纳总结了关键影响因素,第1,碱铝硅酸盐玻璃的成分及结构是基础,氧化铝有利玻璃网络孔隙增大创造交换通道,氧化钠或氧化锂是离子交换关键物质;第2,对于玻璃组成和结构设计,要求玻璃网络键合度R=O/Si或O/(Si+Al)满足2.15~2.40,碱金属氧化物质量分数大于13%且膨胀系数大于6×10^-6/℃;第3,在化学强化工艺方面,化学强化温度决定离子扩散系数,化学强化时间决定DOL,一步法仅能获得相对较大的CS,而DOL不很理想,只有两种离子参与交换的二步法才有利于CS和DOL同步提高。 相似文献
77.
Water and sanitation regulation in Brazil shall be addressed as part of a major problem that involves institutional disputes and legal uncertainty. The paper investigates the hypothesis that the complex institutional framework plays a central role in explaining country's poor performance in the sector. Methodology is mainly qualitative, presenting an analysis that shows how political, institutional and legal hurdles play a major role in explaining the government's inability to secure a financially self-sustainable structure to the sector. The paper suggests that empowering the National Water Agency to issue general guidelines may help reducing transaction costs and fostering sector's development. 相似文献
78.
79.
以井下作业面巷道切顶卸压施工设计为对象开展探究,结合具体工程实际,从切顶卸压爆破施工设计和爆破施工分析两个角度,对切顶卸压技术的全面应用进行总结分析,希望能够为其他矿井相似工程的开展提供借鉴与参考。 相似文献
80.
Manoj Kumar Nayak Vinay Shankar Pandey Dharmendra Tripathi Noreen Sher Akbar Oluwole D Makinde 《亚洲传热研究》2020,49(3):1256-1280
The present study aims to investigate the effects of thermal‐diffusion and diffusion‐thermo onan magnetohydrodynamic convective flow of viscous fluids over an exponentially stretching sheet. Thermal radiation effects are also considered in the study. This analysis is carried out in three dimensions and a similarity transformation is adopted to get a set of ordinary differential equations from a set of partial differential equations. And the Fourth‐order Runge‐Kutta method and shooting technique along with the secant method are employed to find out an iterative solution. We also analyze here the influence of the variable magnetic field, nonuniform permeability and variable chemical reaction on the fluid flow. The impact of various pertinent parameters of interest has extensively been explored through graphs and tables. The major findings of the present study are that resistive Lorentz force diminishes the fluid velocity and uplifts the thermal as well as concentration fields. Inclusion of porous matrix improves the viscous drag force which in turn augments wall shear stresses and peters out the heat and mass transfer rates from the sheet. In addition, the thermal expansion coefficient has an inverse relation with temperature. 相似文献